Lin, Rijia and Hou, Jingwei and Li, Mengran and Wang, Zhanke and Ge, Lei 
ORCID: https://orcid.org/0000-0003-2989-0329 and Li, Shichun and Smart, Simon and Zhu, Zhonghua and Bennett, Thomas D. and Chen, Vicki
(2020)
Interfacial engineering of polymer-MOF composite by in situ vitrification.
Chemical Communications, 56 (25).
pp. 3609-3612.
ISSN 1359-7345
Abstract
Non-stoichoimetric crystalline ZIF-62 was used as the filler for a 6FDA-DAM polyimide-based composite membrane. In situ melting and vitrification of ZIF-62 was then performed, to yield the ZIF-62 glass phase (agZIF-62), within the polymer matrix. Focus ion beam scanning electron microscopy (FIB-SEM), thermal characterisation and membrane separation tests demonstrate the filling of voids at the MOF/polymer interface from the liquid phase of ZIF-62.
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| Item Type: | Article (Commonwealth Reporting Category C) |
|---|---|
| Refereed: | Yes |
| Item Status: | Live Archive |
| Faculty/School / Institute/Centre: | Current - Institute for Advanced Engineering and Space Sciences - Centre for Future Materials (1 Jan 2017 -) |
| Faculty/School / Institute/Centre: | Current - Institute for Advanced Engineering and Space Sciences - Centre for Future Materials (1 Jan 2017 -) |
| Date Deposited: | 13 Jul 2020 04:21 |
| Last Modified: | 27 Jul 2020 01:08 |
| Uncontrolled Keywords: | Mixed-matrix membranes; metal-organic framework; gas separation; performance; liquid; films |
| Fields of Research (2008): | 03 Chemical Sciences > 0303 Macromolecular and Materials Chemistry > 030301 Chemical Characterisation of Materials 09 Engineering > 0904 Chemical Engineering > 090404 Membrane and Separation Technologies |
| Fields of Research (2020): | 34 CHEMICAL SCIENCES > 3403 Macromolecular and materials chemistry > 340399 Macromolecular and materials chemistry not elsewhere classified 40 ENGINEERING > 4004 Chemical engineering > 400409 Separation technologies |
| Socio-Economic Objectives (2008): | E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences |
| Identification Number or DOI: | https://doi.org/10.1039/d0cc00664e |
| URI: | http://eprints.usq.edu.au/id/eprint/38559 |
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