Bronze alloys with tin surface sites for selective electrochemical reduction of CO2

Vasileff, Anthony and Xu, Chaochen and Ge, Lei and Zheng, Yao and Qiao, Shi-Zhang (2018) Bronze alloys with tin surface sites for selective electrochemical reduction of CO2. Chemical Communications, 54 (99). pp. 13965-13968. ISSN 1359-7345

Abstract

Low concentration tin bronze alloys show high selectivity for CO2 electroreduction to CO, while high concentration tin bronze alloys show high selectivity for formate. The tin surface sites appear to control selectivity by influencing the binding characteristics toward the first reaction intermediate on copper-based alloys.


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Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Additional Information: Published version cannot be displayed due to copyright restrictions.
Faculty/School / Institute/Centre: Current - Institute for Advanced Engineering and Space Sciences - Centre for Future Materials
Date Deposited: 05 Feb 2019 02:39
Last Modified: 15 Feb 2019 01:38
Uncontrolled Keywords: electrolytic reduction; electrocatalyst; electrochemical conversion
Fields of Research : 03 Chemical Sciences > 0303 Macromolecular and Materials Chemistry > 030301 Chemical Characterisation of Materials
09 Engineering > 0912 Materials Engineering > 091205 Functional Materials
Socio-Economic Objective: D Environment > 96 Environment > 9603 Climate and Climate Change > 960302 Climate Change Mitigation Strategies
E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences
Identification Number or DOI: 10.1039/c8cc08066f
URI: http://eprints.usq.edu.au/id/eprint/35439

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