Synthesis of zeolite P1 from fly ash under solvent-free conditions for ammonium removal from water

Liu, Yi and Yan, Chunjie and Zhao, Junjie and Zhang, Zuhua and Wang, Hongquan and Zhou, Sen and Wu, Linmei (2018) Synthesis of zeolite P1 from fly ash under solvent-free conditions for ammonium removal from water. Journal of Cleaner Production, 202. pp. 11-22. ISSN 0959-6526

Abstract

In this work, zeolite P1 is synthesized from fluidized bed fly ash (FA) via a solvent-free process. The formation of zeolite P1 is investigated as a function of crystallization reaction time. The solid mixture of FA and Na2SiO3·9H2O with a mole ratio of Na:Al:Si = 1.5:1:1.7 can be converted to zeolite P1 at 80 °C for 24–96 h. XRF, XRD, SEM/EDS, FTIR, TG/DSC and BET techniques are used to test the properties of resultant zeolite products. The efficiencies of the resultant zeolite for ammonium adsorption are evaluated on factors including solution pH, NH4+ ions concentration, temperature and adsorption time. The kinetic data and adsorption equilibrium data fit satisfactory with the Ho's pseudo-second-order kinetic model and Langmuir model. The maximum ammonium adsorption capacity of zeolite P1 (22.9 mg/g) can be reached within 40 min at optimal pH of 6. The adsorption performance is higher than many of the natural zeolites and closely similar to the zeolites synthesized from fly ash through the conventional hydrothermal route. Our study not only provides new insights into the preparation of zeolite from fly ash, but also reveal that the zeolite P1 synthesized through solvent-free route is a promising material for ammonium removal.


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Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Additional Information: Published version cannot be displayed due to copyright restrictions.
Faculty/School / Institute/Centre: Current - Institute for Advanced Engineering and Space Sciences - Centre for Future Materials
Date Deposited: 01 Feb 2019 03:16
Last Modified: 05 Feb 2019 02:10
Uncontrolled Keywords: Zeolite P1; fly ash; solid transformation; absorbent; ammonium removal
Fields of Research : 09 Engineering > 0912 Materials Engineering > 091202 Composite and Hybrid Materials
Socio-Economic Objective: E Expanding Knowledge > 97 Expanding Knowledge > 970109 Expanding Knowledge in Engineering
Funding Details:
Identification Number or DOI: https://doi.org/10.1016/j.jclepro.2018.08.128
URI: http://eprints.usq.edu.au/id/eprint/35283

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