Low temperature molten salt synthesis of perovskite-type ACeO3(A=Sr, Ba) in eutectic NaCl-KCl

Liu, Ming and Hu, Lei and Xu, Pengfei and Zhao, Kun and Zong, Lingbo and Yu, Ranbo and Chen, Jun and Xing, Xianran (2015) Low temperature molten salt synthesis of perovskite-type ACeO3(A=Sr, Ba) in eutectic NaCl-KCl. Chemical Research in Chinese Universities, 31 (3). pp. 342-346. ISSN 1005-9040


A molten salt method was developed for the synthesis of ACeO3(A=Sr, Ba) with perovskite structure at 750 °C(SrCeO3) and 850 °C(BaCeO3) in the eutectic NaCl-KCl. The synthetic temperature was much lower than that of the conventional method(generally>1000 °C). The structure and morphology of the product were characterized by means of X-ray diffraction(XRD), field emission scanning electron microscopy(FESEM) and transmission electron microscopy(TEM). The results show that the synthesized octahedral SrCeO3 crystallizes in the orthorhombic system with the unit cell parameters of a=0.85855 nm, b=0.61523 nm, c=0.60059 nm, and the synthesized cuboid BaCeO3 crystallizes in the cubic system with the unit cell parameter of a=0.43962 nm. The result of X-ray photoelectron spectroscopy(XPS) analysis indicates that both Ce4+ and Ce3+ exist in the two structures, and the Ce4+/Ce3+ peak area ratios for SrCeO3 and BaCeO3 are 1.93 and 2.12, respectively. Meanwhile, the adsorbed/lattice oxygen ratios(1.87 for SrCeO3 and 3.04 for BaCeO3) indicate the existence of a lot of oxygen vacancies in the structures of SrCeO3 and BaCeO3, which indicates a far-reaching significance to study the corresponding physicochemistry performance.

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Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Additional Information: Files associated with this item cannot be displayed due to copyright restrictions.
Faculty/School / Institute/Centre: No Faculty
Faculty/School / Institute/Centre: No Faculty
Date Deposited: 07 Dec 2017 03:44
Last Modified: 28 Aug 2018 03:58
Uncontrolled Keywords: BaCeO3; Molten salt synthesis; Perovskite; SrCeO3;
Fields of Research (2008): 03 Chemical Sciences > 0302 Inorganic Chemistry > 030206 Solid State Chemistry
Fields of Research (2020): 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340210 Solid state chemistry
Socio-Economic Objectives (2008): E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences
Identification Number or DOI: https://doi.org/10.1007/s40242-015-4330-0
URI: http://eprints.usq.edu.au/id/eprint/31938

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