N,N-dimethylformamide-induced synthesis and photoluminescence of CePO4 and Ce0.95PO4:Tb0.05 with sphere-like nanostructures

Bao, Jinrong and Zhu, Xiaowei and Liu, Ying and Li, Wenxian and Yu, Ranbo (2014) N,N-dimethylformamide-induced synthesis and photoluminescence of CePO4 and Ce0.95PO4:Tb0.05 with sphere-like nanostructures. Materials Letters, 124. pp. 97-100. ISSN 0167-577X


Hexagonal CePO4 and Ce0.95PO4:Tb 0.05 uniform sphere-like nanostructures self-assembled by nanowires with about 1-2 μm in length and about 60-70 nm in diameter have been controllably synthesized through the N,N-dimethylformamide-induced hydrothermal route. The morphology, structure, and photoluminescence properties were studied. The results indicated that the N,N-dimethylformamide plays a role in forming the sphere-like nanostructures. By varying the N,N-dimethylformamide concentration, the sphere-like nanostructured CePO4 with a self-assembly of nanowires were controllably synthesized. The hexagonal Ce 0.95PO4:Tb0.05 sphere-like nanostructures exhibited strong photoluminescence. A possible formation mechanism of the sphere-like nanostructures was proposed.

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Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Additional Information: Files associated with this item cannot be displayed due to copyright restrictions.
Faculty/School / Institute/Centre: No Faculty
Faculty/School / Institute/Centre: No Faculty
Date Deposited: 14 Jun 2017 04:57
Last Modified: 14 Jun 2017 04:57
Uncontrolled Keywords: N,N-dimethylformamide; Nanostructure; Orthophosphate; Photoluminescence; Formation mechanism; Hexagonal cepo; Hydrothermal routes; N ,N-Dimethylformamide; Nano-structured; Orthophosphate; Photoluminescence properties; Self-assembled; Fluid Flow; Light and Optics; Nanotechnology; Organic Compounds; Solid State Physics;
Fields of Research (2008): 03 Chemical Sciences > 0303 Macromolecular and Materials Chemistry > 030399 Macromolecular and Materials Chemistry not elsewhere classified
Fields of Research (2020): 34 CHEMICAL SCIENCES > 3403 Macromolecular and materials chemistry > 340399 Macromolecular and materials chemistry not elsewhere classified
Socio-Economic Objectives (2008): E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences
Identification Number or DOI: https://doi.org/10.1016/j.matlet.2014.03.014
URI: http://eprints.usq.edu.au/id/eprint/31922

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