Wu, Long and Yang, Bing Xing and Yang, Xiao Hua and Chen, Zhi Gang and Li, Zhen and Zhao, Hui Jun and Gong, Xue Qing and Yang, Hua Gui (2013) On the synergistic effect of hydrohalic acids in the shape-controlled synthesis of anatase TiO2 single crystals. CrystEngComm, 15 (17). pp. 3252-3255.
Abstract
Cuboid-like anatase TiO2 single crystals bounded by {001} and {100} facets have been successfully synthesized with HCl as a synergistic capping agent together with HF, under the guidance of theoretical calculations. DFT calculations suggest that the preferred replacement of HCl with HF at (100) as well as its favorable adsorption provide a unique stabilization effect on the formation of cuboid-like anatase TiO2.
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| Item Type: | Article (Commonwealth Reporting Category C) |
|---|---|
| Refereed: | Yes |
| Item Status: | Live Archive |
| Additional Information: | Published version cannot be displayed due to copyright restrictions. |
| Faculty / Department / School: | No Faculty |
| Date Deposited: | 27 Jun 2017 23:55 |
| Last Modified: | 27 Jun 2017 23:55 |
| Uncontrolled Keywords: | cuboid-like anatase TiO2; DFT calculations |
| Fields of Research : | 09 Engineering > 0912 Materials Engineering > 091299 Materials Engineering not elsewhere classified 03 Chemical Sciences > 0306 Physical Chemistry (incl. Structural) > 030699 Physical Chemistry not elsewhere classified 03 Chemical Sciences > 0302 Inorganic Chemistry > 030299 Inorganic Chemistry not elsewhere classified |
| Socio-Economic Objective: | E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences |
| Identification Number or DOI: | 10.1039/c2ce26744f |
| URI: | http://eprints.usq.edu.au/id/eprint/31712 |
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