Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties

Song, Pingan ORCID: https://orcid.org/0000-0003-1082-652X and Cao, Zhenhu and Cai, Yuanzheng and Zhao, Liping and Fang, Zhengping and Fu, Shenyuan (2011) Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties. Polymer, 52 (18). pp. 4001-4010. ISSN 0032-3861


Abstract: Despite the great potential of graphene as the nanofiller, to achieve homogeneous dispersion remains the key challenge for effectively reinforcing the polymer. Here, we report an eco-friendly strategy for fabricating the polymer nanocomposites with well-dispersed graphene sheets in the polymer matrix via first coating graphene using polypropylene (PP) latex and then melt-blending the coated graphene with PP matrix. A ∼75% increase in yield strength and a ∼74% increase in the Young's modulus of PP are achieved by addition of only 0.42 vol% of graphene due to the effective external load transfer. The glass transition temperature of PP is enhanced by ∼2.5 °C by incorporating only 0.041 vol% graphene. The thermal oxidative stability of PP is also remarkably improved with the addition of graphene, for example, compared with neat PP, the initial degradation temperature is enhanced by 26 °C at only 0.42 vol% of graphene loading.

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Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Additional Information: Files associated with this item cannot be displayed due to copyright restrictions.
Faculty/School / Institute/Centre: No Faculty
Faculty/School / Institute/Centre: No Faculty
Date Deposited: 05 Jun 2017 22:30
Last Modified: 24 Nov 2021 00:33
Uncontrolled Keywords: grapheme; polypropylene; mechanical properties; thermal properties
Fields of Research (2008): 03 Chemical Sciences > 0303 Macromolecular and Materials Chemistry > 030304 Physical Chemistry of Materials
Fields of Research (2020): 34 CHEMICAL SCIENCES > 3403 Macromolecular and materials chemistry > 340305 Physical properties of materials
Socio-Economic Objectives (2008): E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences
Identification Number or DOI: https://doi.org/10.1016/j.polymer.2011.06.045
URI: http://eprints.usq.edu.au/id/eprint/31643

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