Functionalizing graphene decorated with phosphorus-nitrogen containing dendrimer for high-performance polymer nanocomposites

Jin, Yanxian and Huang, Guobo and Han, Deman and Song, Pingan ORCID: https://orcid.org/0000-0003-1082-652X and Tang, Wenyuan and Bao, Jianshe and Li, Rongrong and Liu, Yilin (2016) Functionalizing graphene decorated with phosphorus-nitrogen containing dendrimer for high-performance polymer nanocomposites. Composites Part A: Applied Science and Manufacturing, 86. pp. 9-18. ISSN 1359-835X


Abstract

In this paper, we demonstrate a novel strategy for fabricating advanced polymer composites based on functionalized graphene oxide decorated with phosphorus-nitrogen-containing dendrimers (PND-GO). Both X-ray diffraction and transmission electron microscopy results show that reduced PND-GO uniformly disperses within polymer matrix and is exfoliated in polyurethane (PU) via in situ polymerization. Cone calorimetry results show that incorporating 2 wt% reduced PND-GO into PU decreases the peak heat release rate by 53% and prolongs the time to ignition by 28 s as compared with the PU bulk. Besides, the tensile strength and Young's modulus are remarkably enhanced by about 2 times and 5 times, respectively.


Statistics for USQ ePrint 31624
Statistics for this ePrint Item
Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Additional Information: Files associated with this item cannot be displayed due to copyright restrictions.
Faculty/School / Institute/Centre: No Faculty
Faculty/School / Institute/Centre: No Faculty
Date Deposited: 24 May 2017 07:31
Last Modified: 24 May 2017 07:31
Uncontrolled Keywords: A. Nano-structures; A. Polymer-matrix composites (PMCs); B. Thermal properties; Graphene; Advanced polymer composites; Cone calorimetry; Functionalized graphene; High performance polymer; In-situ polymerization; Novel strategies; Peak heat release rates; Polymer Matrix Composites (PMCs); Fuel Combustion; Optical Devices and Systems; Nanotechnology; Chemical Products Generally; Polymeric Materials; Solid State Physics; Materials Science; FLUIDEX; Related Topics;
Fields of Research (2008): 09 Engineering > 0912 Materials Engineering > 091209 Polymers and Plastics
Fields of Research (2020): 40 ENGINEERING > 4016 Materials engineering > 401609 Polymers and plastics
Socio-Economic Objectives (2008): B Economic Development > 87 Construction > 8703 Construction Materials Performance and Processes > 870303 Polymeric Materials (e.g. Paints)
Identification Number or DOI: https://doi.org/10.1016/j.compositesa.2016.03.030
URI: http://eprints.usq.edu.au/id/eprint/31624

Actions (login required)

View Item Archive Repository Staff Only