Silitonga, A. S. and Masjuki, H. H. and Ong, Hwai Chyuan and Kusumo, F. and Yusaf, Talal and Mahlia, T. M. I. (2016) Synthesis and optimization of Hevea brasiliensis and Ricinus communis as feedstock for biodiesel production: a comparative study. Industrial Crops and Products, 85. pp. 274-286. ISSN 0926-6690
Abstract
Biodiesel from non-edible seeds has attracted the attention of the authors to investigate Hevea brasiliensis (HB) and Ricinus communis (RC) as potential feedstocks. Biodiesel production was carried out using esterification-neutralization-transesterification (ENT) process. The transesterification process was carried out under variation methanol to oil molar ratio, catalyst concentration, reaction temperature, reaction time and speed agitation. On top of that, optimization was evaluated using Response Surface Methodology (RSM) and a quadratic polynomial model for ENT method. The optimization results show that production biodiesel from HBME and RCME with ENT method were 99.32% and 99.07% respectively. All the properties measured for produced methyl ester met in ASTMD 6751. Moreover, the presence of ricinoleic (α-elaeostearic) in RCME can improve the cold point, pour point and cold filter plugging point, which resulted in -40.4 °C, -27.8 °C and -35.0 °C respectively. The results of the cold flow properties are better due to higher unsaturated fatty acid concentration. It is indicates that RCME has good performance during cold weather engine operation. It short, biodiesel production using ENT method can produce high methyl ester yield and good biodiesel properties.
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| Item Type: | Article (Commonwealth Reporting Category C) |
|---|---|
| Refereed: | Yes |
| Item Status: | Live Archive |
| Additional Information: | Permanent restricted access to published version, in accordance with the copyright policy of the publisher. |
| Faculty/School / Institute/Centre: | Current - Faculty of Health, Engineering and Sciences - School of Mechanical and Electrical Engineering (1 Jul 2013 -) |
| Faculty/School / Institute/Centre: | Current - Faculty of Health, Engineering and Sciences - School of Mechanical and Electrical Engineering (1 Jul 2013 -) |
| Date Deposited: | 04 May 2017 01:05 |
| Last Modified: | 04 May 2017 02:46 |
| Uncontrolled Keywords: | biodiesel; Hevea brasiliensis; Ricinus communis; esterification neutralization transesterification; response surface methodology; alternative fuel |
| Fields of Research (2008): | 09 Engineering > 0902 Automotive Engineering > 090201 Automotive Combustion and Fuel Engineering (incl. Alternative/Renewable Fuels) |
| Identification Number or DOI: | https://doi.org/10.1016/j.indcrop.2016.03.017 |
| URI: | http://eprints.usq.edu.au/id/eprint/31191 |
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