Polymer supported naphthalene-catalysed sodium reactions

van den Ancker, Tania R. and Love, Cameron J. (2007) Polymer supported naphthalene-catalysed sodium reactions. Organic and Biomolecular Chemistry, 5 (21). pp. 3520-3523. ISSN 1477-0520

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Abstract

Arene-catalysed sodium reactions have been utilised in the generation of organosodium complexes, from a variety of organochloride complexes, in high yield. Phenyltrimethylsilane, benzene and 2-methyl-1-phenyl-1-propanol were prepared in yields >80%, using polymer supported naphthalene-catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and polymer-supported naphthalene (5-100%), was quenched with chlorotrimethylsilane, water or PriCHO respectively.


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Item Type: Article (Commonwealth Reporting Category C)
Refereed: Yes
Item Status: Live Archive
Depositing User: Ms Debbie White
Faculty / Department / School: Historic - Faculty of Sciences - Department of Biological and Physical Sciences
Date Deposited: 14 Apr 2008 00:51
Last Modified: 02 Jul 2013 22:52
Uncontrolled Keywords: organosodium complexes; phenylsodium; chlorobenzene; chlorotrimethylsilane; organosodium complexes; sodium powder
Fields of Research (FOR2008): 03 Chemical Sciences > 0304 Medicinal and Biomolecular Chemistry > 030499 Medicinal and Biomolecular Chemistry not elsewhere classified
10 Technology > 1003 Industrial Biotechnology > 100399 Industrial Biotechnology not elsewhere classified
03 Chemical Sciences > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis
Socio-Economic Objective (SEO2008): E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences
Identification Number or DOI: doi: 10.1039/b710308e
URI: http://eprints.usq.edu.au/id/eprint/3445

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