van den Ancker, Tania R. and Love, Cameron J. (2007) Polymer supported naphthalene-catalysed sodium reactions. Organic and Biomolecular Chemistry, 5 (21). pp. 3520-3523. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/Content/ArticlePDF/2007/OB/B710308E/2007-09-20?page=Search
Identification Number or DOI: doi: 10.1039/b710308e
Abstract
Arene-catalysed sodium reactions have been utilised in the generation of organosodium complexes, from a variety of organochloride complexes, in high yield. Phenyltrimethylsilane, benzene and 2-methyl-1-phenyl-1-propanol were prepared in yields >80%, using polymer supported naphthalene-catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and polymer-supported naphthalene (5-100%), was quenched with chlorotrimethylsilane, water or PriCHO respectively.
| Item Type: | Article (Commonwealth Reporting Category C) |
|---|---|
| Uncontrolled Keywords: | organosodium complexes; phenylsodium; chlorobenzene; chlorotrimethylsilane; organosodium complexes; sodium powder |
| Fields of Research (FOR2008): | 03 Chemical Sciences > 0304 Medicinal and Biomolecular Chemistry > 030499 Medicinal and Biomolecular Chemistry not elsewhere classified 10 Technology > 1003 Industrial Biotechnology > 100399 Industrial Biotechnology not elsewhere classified 03 Chemical Sciences > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis |
| Subjects: | 250000 Chemical Sciences > 250300 Organic Chemistry |
| Socio-Economic Objective (SEO2008): | E Expanding Knowledge > 97 Expanding Knowledge > 970103 Expanding Knowledge in the Chemical Sciences |
| ID Code: | 3445 |
| Deposited By: | |
| Deposited On: | 14 Apr 2008 10:51 |
| Last Modified: | 10 Feb 2012 15:21 |
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