van den Ancker, Tania R. and Love, Cameron J. (2007) Polymer supported naphthalene-catalysed sodium reactions. Organic and Biomolecular Chemistry, 5 (21). pp. 3520-3523. ISSN 1477-0520
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Arene-catalysed sodium reactions have been utilised in the generation of organosodium complexes, from a variety of organochloride complexes, in high yield. Phenyltrimethylsilane, benzene and 2-methyl-1-phenyl-1-propanol were prepared in yields >80%, using polymer supported naphthalene-catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and polymer-supported naphthalene (5-100%), was quenched with chlorotrimethylsilane, water or PriCHO respectively.
|Item Type:||Article (Commonwealth Reporting Category C)|
|Uncontrolled Keywords:||organosodium complexes; phenylsodium; chlorobenzene; chlorotrimethylsilane; organosodium complexes; sodium powder|
|Subjects:||250000 Chemical Sciences > 250300 Organic Chemistry|
|Depositing User:||Ms Debbie White|
|Date Deposited:||14 Apr 2008 00:51|
|Last Modified:||02 Jul 2013 22:52|
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